Nonlinear Effects in Asymmetric Catalysis: Some Recent Aspects.
نویسندگان
چکیده
منابع مشابه
Recent Advances in Asymmetric Catalysis in Flow
Asymmetric catalysis in flow has been attracting much attention very recently because of the potential advantages over its batchwise counterpart, such as highthroughput screening and synthesis, easy automation with the integration of on-demand reaction analysis, little or no reaction workup, and potential long-term use of the catalysts in the case of heterogeneous catalysis. Homogeneous asymmet...
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One possible way to take advantage of such abilities may be to apply a ‘combined acids system’ [2] to the catalyst design. The concept of combined acids, which can be classified into Brønsted acid-assisted Lewis acid (BLA), Lewis acid-assisted Lewis acid (LLA), Lewis acid-assisted Brønsted acid (LBA), and Brønsted acid-assisted Brønsted acid (BBA), can be a particularly useful tool for the desi...
متن کاملExpansion of the Concept of Nonlinear Effects in Catalytic Reactions Beyond Asymmetric Catalysis.
The observation and investigation of nonlinear effects in catalytic reactions provides valuable mechanistic insight. However, the applicability of this method was, until now, limited to molecules possessing chirality and therefore to asymmetric synthesis. The concept of nonlinear effects is expanded to catalytic reactions beyond asymmetric catalysis by using derivatives instead of enantiomers a...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1996
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.50-0345